prsm_data =
{
    "prsm": {
        "prsm_id": "93",
        "p_value": "0.05",
        "e_value": "0.06",
        "fdr": "0",
        "matched_fragment_number": "5",
        "matched_peak_number": "5",
        "ms": {
            "ms_header": {
                "spectrum_file_name": "C:/toppic_tutorial/tutorial_3/ecoli_1_ms2.msalign",
                "ms1_ids": "589",
                "ms1_scans": "821",
                "ids": "232",
                "scans": "823",
                "precursor_mono_mass": "9097.7007",
                "precursor_charge": "5",
                "precursor_mz": "1820.5474",
                "feature_inte": "2.5772e+06"
            },
            "peaks": {
                "peak": [
                    {
                        "spec_id": "232",
                        "peak_id": "0",
                        "monoisotopic_mass": "2454.1886",
                        "monoisotopic_mz": "2455.1958",
                        "intensity": "1653.08",
                        "charge": "1",
                        "matched_ions_num": "1",
                        "matched_ions": {
                            "matched_ion": {
                                "ion_type": "Y",
                                "match_shift": "0.0000000000",
                                "theoretical_mass": "2454.1948",
                                "ion_position": "63",
                                "ion_display_position": "22",
                                "ion_sort_name": "Y00022",
                                "ion_left_position": "63",
                                "mass_error": "-0.0062",
                                "ppm": "-2.55"
                            }
                        }
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "1",
                        "monoisotopic_mass": "1722.3974",
                        "monoisotopic_mz": "1723.4047",
                        "intensity": "1694.72",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "2",
                        "monoisotopic_mass": "2259.2232",
                        "monoisotopic_mz": "1130.6189",
                        "intensity": "1165.82",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "3",
                        "monoisotopic_mass": "832.4405",
                        "monoisotopic_mz": "833.4478",
                        "intensity": "1081.52",
                        "charge": "1",
                        "matched_ions_num": "1",
                        "matched_ions": {
                            "matched_ion": {
                                "ion_type": "Y",
                                "match_shift": "0.0000000000",
                                "theoretical_mass": "832.4364",
                                "ion_position": "78",
                                "ion_display_position": "7",
                                "ion_sort_name": "Y00007",
                                "ion_left_position": "78",
                                "mass_error": "0.0041",
                                "ppm": "4.92"
                            }
                        }
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "4",
                        "monoisotopic_mass": "3692.2846",
                        "monoisotopic_mz": "1847.1496",
                        "intensity": "1795.64",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "5",
                        "monoisotopic_mass": "663.2718",
                        "monoisotopic_mz": "664.2791",
                        "intensity": "1252.76",
                        "charge": "1",
                        "matched_ions_num": "1",
                        "matched_ions": {
                            "matched_ion": {
                                "ion_type": "B",
                                "match_shift": "0.0000000000",
                                "theoretical_mass": "663.2686",
                                "ion_position": "5",
                                "ion_display_position": "5",
                                "ion_sort_name": "B00005",
                                "ion_left_position": "5",
                                "mass_error": "0.0032",
                                "ppm": "4.81"
                            }
                        }
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "6",
                        "monoisotopic_mass": "1149.0920",
                        "monoisotopic_mz": "1150.0992",
                        "intensity": "767.36",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "7",
                        "monoisotopic_mass": "2281.2067",
                        "monoisotopic_mz": "1141.6106",
                        "intensity": "2367.34",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "8",
                        "monoisotopic_mass": "1434.7424",
                        "monoisotopic_mz": "1435.7496",
                        "intensity": "1640.26",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "9",
                        "monoisotopic_mass": "1735.5024",
                        "monoisotopic_mz": "1736.5096",
                        "intensity": "964.89",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "10",
                        "monoisotopic_mass": "1162.7205",
                        "monoisotopic_mz": "1163.7278",
                        "intensity": "319.35",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "11",
                        "monoisotopic_mass": "1803.9253",
                        "monoisotopic_mz": "1804.9325",
                        "intensity": "1160.77",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "12",
                        "monoisotopic_mass": "5453.7995",
                        "monoisotopic_mz": "1818.9404",
                        "intensity": "5232.56",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "13",
                        "monoisotopic_mass": "1389.8606",
                        "monoisotopic_mz": "1390.8679",
                        "intensity": "314.32",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "14",
                        "monoisotopic_mass": "1310.7953",
                        "monoisotopic_mz": "1311.8026",
                        "intensity": "981.74",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "15",
                        "monoisotopic_mass": "4819.9505",
                        "monoisotopic_mz": "1607.6574",
                        "intensity": "1074.21",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "16",
                        "monoisotopic_mass": "1455.0137",
                        "monoisotopic_mz": "1456.0210",
                        "intensity": "334.90",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "17",
                        "monoisotopic_mass": "3258.6601",
                        "monoisotopic_mz": "1630.3373",
                        "intensity": "905.63",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "18",
                        "monoisotopic_mass": "762.3409",
                        "monoisotopic_mz": "763.3481",
                        "intensity": "553.99",
                        "charge": "1",
                        "matched_ions_num": "1",
                        "matched_ions": {
                            "matched_ion": {
                                "ion_type": "B",
                                "match_shift": "0.0000000000",
                                "theoretical_mass": "762.3371",
                                "ion_position": "6",
                                "ion_display_position": "6",
                                "ion_sort_name": "B00006",
                                "ion_left_position": "6",
                                "mass_error": "0.0038",
                                "ppm": "5.00"
                            }
                        }
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "19",
                        "monoisotopic_mass": "1247.7707",
                        "monoisotopic_mz": "1248.7780",
                        "intensity": "373.16",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "20",
                        "monoisotopic_mass": "3060.5724",
                        "monoisotopic_mz": "1531.2935",
                        "intensity": "1090.67",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "21",
                        "monoisotopic_mass": "7661.6599",
                        "monoisotopic_mz": "1533.3393",
                        "intensity": "1117.31",
                        "charge": "5"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "22",
                        "monoisotopic_mass": "5417.7617",
                        "monoisotopic_mz": "1806.9279",
                        "intensity": "3645.01",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "23",
                        "monoisotopic_mass": "4806.3908",
                        "monoisotopic_mz": "1603.1375",
                        "intensity": "1834.06",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "24",
                        "monoisotopic_mass": "3865.9868",
                        "monoisotopic_mz": "1934.0007",
                        "intensity": "851.54",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "25",
                        "monoisotopic_mass": "6205.6425",
                        "monoisotopic_mz": "1552.4179",
                        "intensity": "580.35",
                        "charge": "4"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "26",
                        "monoisotopic_mass": "4851.6726",
                        "monoisotopic_mz": "1618.2315",
                        "intensity": "1140.86",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "27",
                        "monoisotopic_mass": "1789.9538",
                        "monoisotopic_mz": "1790.9611",
                        "intensity": "861.30",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "28",
                        "monoisotopic_mass": "3999.0264",
                        "monoisotopic_mz": "2000.5205",
                        "intensity": "550.92",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "29",
                        "monoisotopic_mass": "8553.2841",
                        "monoisotopic_mz": "1711.6641",
                        "intensity": "2013.21",
                        "charge": "5"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "30",
                        "monoisotopic_mass": "3345.8051",
                        "monoisotopic_mz": "1673.9098",
                        "intensity": "571.93",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "31",
                        "monoisotopic_mass": "5435.7764",
                        "monoisotopic_mz": "1812.9327",
                        "intensity": "4695.62",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "32",
                        "monoisotopic_mass": "1559.8313",
                        "monoisotopic_mz": "1560.8386",
                        "intensity": "759.22",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "33",
                        "monoisotopic_mass": "1829.2605",
                        "monoisotopic_mz": "1830.2678",
                        "intensity": "806.66",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "34",
                        "monoisotopic_mass": "7784.8279",
                        "monoisotopic_mz": "1557.9729",
                        "intensity": "565.92",
                        "charge": "5"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "35",
                        "monoisotopic_mass": "3604.2198",
                        "monoisotopic_mz": "1803.1172",
                        "intensity": "596.96",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "36",
                        "monoisotopic_mass": "6528.5111",
                        "monoisotopic_mz": "1306.7095",
                        "intensity": "745.62",
                        "charge": "5",
                        "matched_ions_num": "1",
                        "matched_ions": {
                            "matched_ion": {
                                "ion_type": "B",
                                "match_shift": "-16.9440374125",
                                "theoretical_mass": "6529.5144",
                                "ion_position": "62",
                                "ion_display_position": "62",
                                "ion_sort_name": "B00062",
                                "ion_left_position": "62",
                                "mass_error": "-0.0010",
                                "ppm": "-0.16"
                            }
                        }
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "37",
                        "monoisotopic_mass": "7359.5588",
                        "monoisotopic_mz": "1472.9190",
                        "intensity": "606.15",
                        "charge": "5"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "38",
                        "monoisotopic_mass": "1275.1737",
                        "monoisotopic_mz": "1276.1810",
                        "intensity": "373.47",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "39",
                        "monoisotopic_mass": "8343.0801",
                        "monoisotopic_mz": "1669.6233",
                        "intensity": "1140.35",
                        "charge": "5"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "40",
                        "monoisotopic_mass": "6141.0876",
                        "monoisotopic_mz": "1536.2792",
                        "intensity": "1489.39",
                        "charge": "4"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "41",
                        "monoisotopic_mass": "1673.0263",
                        "monoisotopic_mz": "1674.0336",
                        "intensity": "816.12",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "42",
                        "monoisotopic_mass": "1488.2595",
                        "monoisotopic_mz": "1489.2667",
                        "intensity": "307.58",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "43",
                        "monoisotopic_mass": "4640.2965",
                        "monoisotopic_mz": "1547.7728",
                        "intensity": "559.88",
                        "charge": "3"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "44",
                        "monoisotopic_mass": "1417.7277",
                        "monoisotopic_mz": "1418.7350",
                        "intensity": "331.29",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "45",
                        "monoisotopic_mass": "5473.7969",
                        "monoisotopic_mz": "1369.4565",
                        "intensity": "683.46",
                        "charge": "4"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "46",
                        "monoisotopic_mass": "1626.0005",
                        "monoisotopic_mz": "1627.0078",
                        "intensity": "1236.92",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "47",
                        "monoisotopic_mass": "3491.1477",
                        "monoisotopic_mz": "1746.5811",
                        "intensity": "571.25",
                        "charge": "2"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "48",
                        "monoisotopic_mass": "7570.1045",
                        "monoisotopic_mz": "1515.0282",
                        "intensity": "653.10",
                        "charge": "5"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "49",
                        "monoisotopic_mass": "1376.7155",
                        "monoisotopic_mz": "1377.7228",
                        "intensity": "286.28",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "50",
                        "monoisotopic_mass": "1360.5187",
                        "monoisotopic_mz": "1361.5260",
                        "intensity": "317.32",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "51",
                        "monoisotopic_mass": "1401.9770",
                        "monoisotopic_mz": "1402.9843",
                        "intensity": "366.54",
                        "charge": "1"
                    },
                    {
                        "spec_id": "232",
                        "peak_id": "52",
                        "monoisotopic_mass": "1340.3245",
                        "monoisotopic_mz": "1341.3318",
                        "intensity": "298.37",
                        "charge": "1"
                    }
                ]
            }
        },
        "annotated_protein": {
            "sequence_id": "1",
            "proteoform_id": "57",
            "sequence_name": "sp|P0AA04|PTHP_ECOLI",
            "sequence_description": "Phosphocarrier protein HPr OS=Escherichia coli (strain K12) OX=83333 GN=ptsH PE=1 SV=1",
            "proteoform_mass": "9096.7933",
            "n_acetylation": "0",
            "unexpected_shift_number": "1",
            "annotation": {
                "protein_length": "85",
                "first_residue_position": "0",
                "last_residue_position": "84",
                "annotated_seq": ".MFQQEV(TITAPNGLHTRPAAQFVKEAKGFTSEITVTSNGKSASAKSLFKLQTLGLTQGTVVT)[-16.9440]ISAEGEDEQKAVEHLVKLMAELE.",
                "residue": [
                    {
                        "position": "0",
                        "acid": "M"
                    },
                    {
                        "position": "1",
                        "acid": "F"
                    },
                    {
                        "position": "2",
                        "acid": "Q"
                    },
                    {
                        "position": "3",
                        "acid": "Q"
                    },
                    {
                        "position": "4",
                        "acid": "E"
                    },
                    {
                        "position": "5",
                        "acid": "V"
                    },
                    {
                        "position": "6",
                        "acid": "T"
                    },
                    {
                        "position": "7",
                        "acid": "I"
                    },
                    {
                        "position": "8",
                        "acid": "T"
                    },
                    {
                        "position": "9",
                        "acid": "A"
                    },
                    {
                        "position": "10",
                        "acid": "P"
                    },
                    {
                        "position": "11",
                        "acid": "N"
                    },
                    {
                        "position": "12",
                        "acid": "G"
                    },
                    {
                        "position": "13",
                        "acid": "L"
                    },
                    {
                        "position": "14",
                        "acid": "H"
                    },
                    {
                        "position": "15",
                        "acid": "T"
                    },
                    {
                        "position": "16",
                        "acid": "R"
                    },
                    {
                        "position": "17",
                        "acid": "P"
                    },
                    {
                        "position": "18",
                        "acid": "A"
                    },
                    {
                        "position": "19",
                        "acid": "A"
                    },
                    {
                        "position": "20",
                        "acid": "Q"
                    },
                    {
                        "position": "21",
                        "acid": "F"
                    },
                    {
                        "position": "22",
                        "acid": "V"
                    },
                    {
                        "position": "23",
                        "acid": "K"
                    },
                    {
                        "position": "24",
                        "acid": "E"
                    },
                    {
                        "position": "25",
                        "acid": "A"
                    },
                    {
                        "position": "26",
                        "acid": "K"
                    },
                    {
                        "position": "27",
                        "acid": "G"
                    },
                    {
                        "position": "28",
                        "acid": "F"
                    },
                    {
                        "position": "29",
                        "acid": "T"
                    },
                    {
                        "position": "30",
                        "acid": "S"
                    },
                    {
                        "position": "31",
                        "acid": "E"
                    },
                    {
                        "position": "32",
                        "acid": "I"
                    },
                    {
                        "position": "33",
                        "acid": "T"
                    },
                    {
                        "position": "34",
                        "acid": "V"
                    },
                    {
                        "position": "35",
                        "acid": "T"
                    },
                    {
                        "position": "36",
                        "acid": "S"
                    },
                    {
                        "position": "37",
                        "acid": "N"
                    },
                    {
                        "position": "38",
                        "acid": "G"
                    },
                    {
                        "position": "39",
                        "acid": "K"
                    },
                    {
                        "position": "40",
                        "acid": "S"
                    },
                    {
                        "position": "41",
                        "acid": "A"
                    },
                    {
                        "position": "42",
                        "acid": "S"
                    },
                    {
                        "position": "43",
                        "acid": "A"
                    },
                    {
                        "position": "44",
                        "acid": "K"
                    },
                    {
                        "position": "45",
                        "acid": "S"
                    },
                    {
                        "position": "46",
                        "acid": "L"
                    },
                    {
                        "position": "47",
                        "acid": "F"
                    },
                    {
                        "position": "48",
                        "acid": "K"
                    },
                    {
                        "position": "49",
                        "acid": "L"
                    },
                    {
                        "position": "50",
                        "acid": "Q"
                    },
                    {
                        "position": "51",
                        "acid": "T"
                    },
                    {
                        "position": "52",
                        "acid": "L"
                    },
                    {
                        "position": "53",
                        "acid": "G"
                    },
                    {
                        "position": "54",
                        "acid": "L"
                    },
                    {
                        "position": "55",
                        "acid": "T"
                    },
                    {
                        "position": "56",
                        "acid": "Q"
                    },
                    {
                        "position": "57",
                        "acid": "G"
                    },
                    {
                        "position": "58",
                        "acid": "T"
                    },
                    {
                        "position": "59",
                        "acid": "V"
                    },
                    {
                        "position": "60",
                        "acid": "V"
                    },
                    {
                        "position": "61",
                        "acid": "T"
                    },
                    {
                        "position": "62",
                        "acid": "I"
                    },
                    {
                        "position": "63",
                        "acid": "S"
                    },
                    {
                        "position": "64",
                        "acid": "A"
                    },
                    {
                        "position": "65",
                        "acid": "E"
                    },
                    {
                        "position": "66",
                        "acid": "G"
                    },
                    {
                        "position": "67",
                        "acid": "E"
                    },
                    {
                        "position": "68",
                        "acid": "D"
                    },
                    {
                        "position": "69",
                        "acid": "E"
                    },
                    {
                        "position": "70",
                        "acid": "Q"
                    },
                    {
                        "position": "71",
                        "acid": "K"
                    },
                    {
                        "position": "72",
                        "acid": "A"
                    },
                    {
                        "position": "73",
                        "acid": "V"
                    },
                    {
                        "position": "74",
                        "acid": "E"
                    },
                    {
                        "position": "75",
                        "acid": "H"
                    },
                    {
                        "position": "76",
                        "acid": "L"
                    },
                    {
                        "position": "77",
                        "acid": "V"
                    },
                    {
                        "position": "78",
                        "acid": "K"
                    },
                    {
                        "position": "79",
                        "acid": "L"
                    },
                    {
                        "position": "80",
                        "acid": "M"
                    },
                    {
                        "position": "81",
                        "acid": "A"
                    },
                    {
                        "position": "82",
                        "acid": "E"
                    },
                    {
                        "position": "83",
                        "acid": "L"
                    },
                    {
                        "position": "84",
                        "acid": "E"
                    }
                ],
                "cleavage": [
                    {
                        "position": "0",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "1",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "2",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "3",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "4",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "5",
                        "exist_n_ion": "1",
                        "exist_c_ion": "0",
                        "matched_peaks": {
                            "matched_peak": {
                                "ion_type": "B",
                                "ion_position": "5",
                                "ion_display_position": "5",
                                "spec_id": "232",
                                "peak_id": "5",
                                "peak_charge": "1"
                            }
                        }
                    },
                    {
                        "position": "6",
                        "exist_n_ion": "1",
                        "exist_c_ion": "0",
                        "matched_peaks": {
                            "matched_peak": {
                                "ion_type": "B",
                                "ion_position": "6",
                                "ion_display_position": "6",
                                "spec_id": "232",
                                "peak_id": "18",
                                "peak_charge": "1"
                            }
                        }
                    },
                    {
                        "position": "7",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "8",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "9",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "10",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "11",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "12",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "13",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "14",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "15",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "16",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "17",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "18",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "19",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "20",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "21",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "22",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "23",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "24",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "25",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "26",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "27",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "28",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "29",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "30",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "31",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "32",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "33",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "34",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "35",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "36",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "37",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "38",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "39",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "40",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "41",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "42",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "43",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "44",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "45",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "46",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "47",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "48",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "49",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "50",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "51",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "52",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "53",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "54",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "55",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "56",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "57",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "58",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "59",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "60",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "61",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "62",
                        "exist_n_ion": "1",
                        "exist_c_ion": "0",
                        "matched_peaks": {
                            "matched_peak": {
                                "ion_type": "B",
                                "ion_position": "62",
                                "ion_display_position": "62",
                                "spec_id": "232",
                                "peak_id": "36",
                                "peak_charge": "5"
                            }
                        }
                    },
                    {
                        "position": "63",
                        "exist_n_ion": "0",
                        "exist_c_ion": "1",
                        "matched_peaks": {
                            "matched_peak": {
                                "ion_type": "Y",
                                "ion_position": "63",
                                "ion_display_position": "22",
                                "spec_id": "232",
                                "peak_id": "0",
                                "peak_charge": "1"
                            }
                        }
                    },
                    {
                        "position": "64",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "65",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "66",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "67",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "68",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "69",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "70",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "71",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "72",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "73",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "74",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "75",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "76",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "77",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "78",
                        "exist_n_ion": "0",
                        "exist_c_ion": "1",
                        "matched_peaks": {
                            "matched_peak": {
                                "ion_type": "Y",
                                "ion_position": "78",
                                "ion_display_position": "7",
                                "spec_id": "232",
                                "peak_id": "3",
                                "peak_charge": "1"
                            }
                        }
                    },
                    {
                        "position": "79",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "80",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "81",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "82",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "83",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "84",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    },
                    {
                        "position": "85",
                        "exist_n_ion": "0",
                        "exist_c_ion": "0",
                        "matched_peaks": null
                    }
                ],
                "mass_shift": {
                    "id": "0",
                    "left_position": "6",
                    "right_position": "62",
                    "shift": "-16.9440374125",
                    "anno": "-16.9440",
                    "shift_type": "unexpected"
                }
            }
        }
    }
}
